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    • 专利摘要:
    Additive formulation for asphalts, method of obtaining and use in the regeneration of road surfaces. The present invention relates to a first component, which is a bitumen or a mixture of bitumens, in a percentage comprised between 40% -80% by weight of the total composition and a second component, which is a mixture containing: bitumen, in a percentage comprised between 5% -20% of the total weight of the mixture of the second component, consisting of hydrocarbons having a carbon atom number equal to or greater than 13, and having a boiling point equal to or greater than at 490º c; glycerin, in a percentage comprised between 5% -10%; antioxidant gum, in a percentage equal to or less than 1.50%; a mixture of fatty acids, in a percentage comprised between 1% -30%; a methyl ester, in a percentage comprised between 1% -30%; and paraffin resin, in a percentage comprised between 1% -30%, of the total weight of the mixture of the second component. (Machine-translation by Google Translate, not legally binding)
    公开号:ES2563630A1
    申请号:ES201431327
    申请日:2014-09-15
    公开日:2016-03-15
    发明作者:Yuri Margulis；Mario JIMÉNEZ OCHOA；Miguel Ángel GARCÍA CARRASCOSO
    申请人:Recuperaciones Asfalticas S L；Recuperaciones Asfalticas Sl；
    IPC主号:
    专利说明:

    DESCRIPTION

    ADDITIVE FORMULATION FOR ASPHALTS, METHOD OF OBTAINING AND USE IN ROAD SIGNATURE REGENERATION
     5
    FIELD OF THE INVENTION
    The present invention relates to additive compositions and methods for asphalt regeneration, and is encompassed in the construction and civil works sector, specifically in the area of paving and construction of road signatures.
      10
    STATE OF THE TECHNIQUE
    The sustainable construction of roads is currently not only a necessity, but also an inexcusable duty, and especially when such construction offers numerous opportunities for the reuse of materials, both generated by the work itself and provided from outside. fifteen

    Faced with the technique of firm reinforcement, recycling and reuse of them is shown as a very advantageous alternative to reduce the impact on the environment of this activity. In this sense, the recycling of recyclable asphalt materials or pavements, known in the art field as RAP (from the English reclaimed 20 asphalt pavements), for the execution of new layers is not a novel technique, since it has been known for almost 40 years, but the appearance of specific machinery and the evolution of construction systems, together with a greater concern for all issues related to environmental sustainability, have contributed to a great growth and development of the recycling of firm. However, this practice should be encouraged as 50 million tonnes of RAP waste were produced annually in 2008 (EAPA, 2008: Arguments to stimulate the government to promote asphalt resuse and recycling).

    Currently, recycling can be applied to all the materials that constitute the 30 sections of the firm, using very different methods to be carried out in situ (treating and incorporating the RAP directly in the place from which it was previously extracted) or in plant (extracting the material to be regenerated and taking it to an industrial plant located in another point to later reuse the RAP in the same place from which it was extracted or in another project); cold, warm or hot; and with 35
    contribution or without contribution of new granular material. The reuse methods of hot and cold RAP are used to produce new asphalt, while cold recycling methods are carried out by adding emulsions, bitumen or hydraulic binder (cement). For the application of all these techniques, there is a wide variety of machinery and asphalt plants 5 equipped with the necessary elements to properly process the material to be recycled. In addition to these specific equipment, milling machines and mobile crushing and sorting equipment are also useful in recycling materials.
     10
    Regarding the recycling of pavements by hot bituminous compositions (that is, with heating of the materials until a mixture around 150-180 ºC is obtained that allows the putting into work), it should be noted that its application is conditioned by the weather and the temperature of the medium, so that it is not advisable or advantageous to use it in winter. In addition, it is an expensive process to the extent that it requires the use of virgin aggregates, and it is not possible to recycle more than 15% of the firm to be regenerated (commonly known as RAP). There are also semi-luminous bituminous mixtures, whose manufacturing temperature is reduced with respect to the hot ones up to a temperature between 125ºC-130ºC. twenty

    For its part, tempered bituminous mixtures (put into work at a temperature of around 100ºC, although it may be lower, such as 80ºC) for the regeneration of firm try to improve the technique by reducing the reuse and recycling temperature of the RAP (Miranda Pérez , L. (2012): Temperate and 25 Semi-Asphalt Mixes (paper). Firm Technical Road Conference. Sustainability). Emulsions (with water) are generally used and are not advisable in winter, being their main setback that only allows regenerating a part of the firm in question on which it is applied, also requiring the technical and technological adaptation of the industrial plants where it is manufactured or uses (Vázquez Epifanio, 30 JM (2012): Temperate mixtures: a bet for the future come true (presentation). I National Technical Day of Bituminous Emulsions. Bituminous emulsions: the technique at the service of the road. Organized by CIESM-INTEVIA; Counseling of Public Works and Housing and of the Public Works Agency of the Junta de Andalucía (2012): Recommendations for the drafting of technical specifications 35
    for the use of bituminous mixtures at low temperatures. Technical report, 117 pages).

    Cold asphalt recycling (at room temperature) is, today, the main object of interest in the field of technology for its environmental advantages, 5 there are already various alternatives and improvements in terms of bituminous mixtures to be used ( García Santiago, JL (2012): Recycling bituminous signatures with bituminous emulsion (paper) I. National Technical Day of Bituminous Emulsions Bituminous emulsions: the technique at the service of the road Organized by CIESM-INTEVIA; Ministry of Public Works and Housing and of the Public Works Agency of 10 the Junta de Andalucía (2012): Recommendations for the drafting of technical specifications for the use of bituminous mixtures at low temperatures. Technical report, 117 pages). The compositions or cold mixtures that are known are emulsions that always have a water content, so that under unfavorable conditions it can decompose after the place of regeneration of the firm with which it is mixed has been applied in such a way. way that its application is conditioned by the weather and seasonal conditions. In addition, it requires a certain curing time to pass until the mixture is cohesive and total water loss occurs before the passage of road traffic can be allowed; The asphalt regenerated by means of these cold mixtures must be protected 20 after being applied by a tread, since due to their characteristics they cannot be used as such. One aspect to be taken into account for the regeneration of cold RAP is that this method requires a greater amount of materials (milling and additives) than when building a path with new hot agglomerate to obtain a layer with the same bearing capacity. 25

    From this perspective, it is necessary to investigate and achieve a bituminous binder or mixture sufficiently manageable during the mixing, extension and compaction phase in the reuse and recycling of RAP to allow adequate handling of the agglomerate and lower the working temperature (Potti , JJ (2007): 30 R + D + i on roads IV Andalusian Highway Congress Roads for the 21st Century: commitment to quality and service: 1359-1365) The present invention, which is a bituminous composition with the specifications described below and added to asphalt for regeneration, it is shown as an advantageous alternative in road sign recycling, as is its method of 35
    manufacturing and its cold application mode.
    GENERAL DESCRIPTION OF THE INVENTION
    The first object of the present invention is a bituminous composition that is designed to be added to old asphalts for regeneration, and that functions as a regenerative additive for recyclable asphalt pavements. Said composition comprises:
    - a first component that is a bitumen or a mixture of bitumens in a percentage between 40% and 80% by weight of the total composition; Y
    - a second component that is a mixture that contains: 10
    or a bitumen, in a percentage between 5% and 20% of the total weight of the mixture of the second component, consisting of hydrocarbons with a number of carbon atoms equal to or greater than 13, and having a boiling point equal to or higher than 490 ° C;
    or glycerin, in a percentage between 5% and 10% of the total weight of the mixture of the second component;
    or antioxidant gum, in a percentage equal to or less than 1.50% of the total weight of the mixture of the second component;
    or a mixture of fatty acids, in a percentage between 1% and 30% of the total weight of the mixture of the second component; twenty
    or a methyl ester, in a percentage comprised between 1% and 30% of the total weight of the mixture of the second component; Y
    or paraffin resin, in a percentage between 1% and 30% of the total weight of the mixture of the second component.
     25
    The bituminous composition described is constituted by the fusion of both components, that is to say, in the composition the two components are melted together, and it is stable and liquid at room temperature. In general, a bitumen at room temperature usually appears in the form of a solid block, so that the present bituminous composition presents great advantages and opportunities in the field, because it allows it to be stored in a liquid state prior to its use without the presence of heat to keep it in a liquid state, as is the case with bitumens that are used as raw material in this process. Thus, the composition as described is now ready to be mixed with the milling of the constituent agglomerate of the different types of firm, as an additive, in a process with ranges 35
    of low temperature (see below). It should be noted that, being a composition with a high bitumen content, it has a variable viscosity depending on the temperature. Thus, it has been found that the ambient temperature has a significant impact on its viscosity, such that it ranges between 800 and 200 cps at temperatures between 17 ° C and 30 ° C. 5

    This composition does not contain water, in any way; It is important to mention this fact because, since there is no water in its composition, it can be used for the regeneration of road surfaces without waiting for the product to be cured by the old recycled sign and the bituminous composition, as is the case with mixtures in cold known so far, that being emulsions always contain water that conditions their properties and their uses; in this way, the opening to traffic of the recycled firm with the composition described here is immediate. In addition, one aspect or advantage that should be highlighted as essential in the described composition is that it allows the resulting firm (RAP or milling) with which it is mixed for regeneration directly serves as a tread, showing sufficient bearing capacity for this purpose. by itself without having to be covered by an additional layer to be protected, as even the law requires in several countries (including Spain) for the regeneration of roads with cold mixtures. Generally, the cold recycled RAP used in road regeneration 20 should be covered with another top layer of protection such as a 4 cm thick hot chipboard, or alternatively slurries, but it should always be covered because its properties are not completely suitable to act as a tread, contrary to the RAP that can be recycled and regenerated with the bituminous composition described. 25

    The first component of the bituminous composition may be only a bitumen, or alternatively a mixture of two or more bitumens. The bitumens used in the composition are commercial, and the proportion with which they appear in the composition depends on the type of bitumen used and the type of milling with which the composition is to be mixed, in order to regenerate and reuse it . Commercial bitumens that have shown more interesting results and are therefore preferred in the present composition are those known commercially as 15/25 and 50/70. The proportion of the first component (one or more bitumens) preferably ranges from 60% to 80% of the total weight of the final mixture, 35 being
    preferably 70%.
    On the other hand, the second component can be comprised in the bituminous composition in a percentage comprised between 20% and 60% of the total weight of the composition, without the need for it to comprise a third element. In the most preferred case, the second component is comprised in a percentage of 30%, 5 such that the bituminous composition has a preferred formulation consisting of 70% of the first component and 30% of the second. This preferred case in which the bituminous composition has a proportion between the first component and the second one of 70:30, is especially preferable for the regeneration of roads and roads and for the use of RAP as a tread. 10

    The mixture that constitutes the second component of the bituminous composition is dark in appearance (black color), stable under normal conditions and of liquid-oily consistency, and has a flash point of less than 150 ° C. This mixture is insoluble in water. fifteen

    The bitumen of this second component or mixture comes from the oil refinery, and is specifically a complex residue that comes from the distillation of oil at a temperature equal to or greater than 490 ° C (its boiling point). More specifically, it is a residue obtainable from distillation (for example, under vacuum) of another residue which in turn comes from distillation (for example, at atmospheric pressure) of oil at temperatures above 490 ° C (914 ° F). Preferably, the hydrocarbons constituting the bitumen have a number of carbon atoms equal to or greater than 23, and may be more preferably still equal to or greater than 34, and said bitumen preferably has a boiling point of at least 495 ° C (923 ° F). Bitumen has in this case a CAS number (Chemical Abstracts Service Registry Numbers) as the unique identifier for chemical substances that is 64741-56-6. Bitumen is not a substance classified as dangerous in Annex I of Directive 67/548 / EEC, nor does it appear in the list of Annex I of Regulation (EC) No. 689/2008 on Export and Import of Hazardous Chemicals 30 . In a preferred mode, the bitumen of this mixture is contained in 15% of the total weight of the second component.

    On the other hand, glycerin may preferably be contained in 10% of the total weight of the second component. Also preferably, the antioxidant gum of 35
    The second component is a p-phenylenediamine, and even more preferably N-1,3-dimethylbutyl-N'-phenyl-p-phenylenediamide, which may be contained in a percentage of 1.25%. The fatty acid mixture, which has a CAS number 61789-45-5, may preferably be present in 20% of the total weight of the mixture of the second component, while the methyl ester may be contained in 10% and 5%. 5% paraffinic resin.

    Thus, a preferred embodiment of the bituminous composition comprises:
    - the first component, which is a bitumen or a mixture of bitumens, in a percentage between 40% and 80% by weight of the total composition; Y
    - the second component, which is a mixture that contains:
    or the bitumen consisting of hydrocarbons with a number of carbon atoms equal to or greater than 13, more preferably equal to or greater than 23, and having a boiling point equal to or greater than 490 ° C, 15 more preferably of at least 495 ° C, in a percentage of 15% of the total weight of the mixture of the second component;
    or glycerin, in a percentage of 10% of the total weight of the mixture of the second component;
    or the antioxidant gum, which is N-1,3-dimethylbutyl-N'-phenyl-p-phenylenediamide, 20 in a percentage of 1.25% of the total weight of the mixture of the second component;
    or the fatty acid mixture, in a percentage of 20% of the total weight of the mixture of the second component;
    or the methyl ester, in a percentage of 10% of the total weight of the mixture of the second component; Y
    or the paraffin resin, in a percentage of 5% of the total weight of the mixture of the second component.

    The second component may additionally comprise (even to complete its 100% formulation) one or more additional additives commonly known in the field, or other possible ones that are of interest. Among these additives is not water. Preferably, among the additives that the bituminous composition can incorporate are the contents in the following categories: additives to prevent the formation of grooves, additives to reduce and delay the onset of fatigue; 35
    additives to increase resistance to thermal breakage; additives for the improvement of resistance to furrow formation at high temperatures; additives for improving stiffness values; binding additives or binders; hollow filling additive, to improve stability and improve the bond between elements as binders; additives that improve tensile strength; oxidizing additives that increase the stiffness of the asphalt once mixed with it and extended; antioxidant additives that increase the product's half-life; additives that improve water resistance, and any combination of the types of additives presented.

    Specifically, preferably, the additive or additives that can be incorporated into the mixture of the second component are selected from the group consisting of:
    · An elastomeric polymer of the styrenic type which is SBS (styrene-butadiene-styrene, of the English styrene butadiene styrene), to prevent the formation of grooves, delay and reduce the onset of fatigue and increase the resistance to thermal breakage; fifteen
    · Styrene-butadiene rubber (SBR), to prevent the formation of grooves, delay and reduce the onset of fatigue and increase resistance to thermal breakage;
    · Low density polyethylene (LDPE), to improve resistance to furrow formation at high temperatures; twenty
    · A thermoplastic polymer that is ethyl vinyl acetate, in English ethylene vinyl acetate or EVA, for the improvement of resistance to furrow formation at high temperature;
    · A thermoplastic polymer that is ethylene-propylene, from English EPMD or ethylene propylene, for the improvement of thermal breakage resistance; 25
    · Crumb rubber, known as crumb rubber, to prevent the formation of grooves, delay and reduce the onset of fatigue and increase resistance to thermal breakage;
    · Polyphosphoric acid (PPVA), to improve resistance to high temperatures; 30
    · Sulfur and / or lignin, as a binder or binder;
    · Lime, to fill gaps, increase stability and improve the bond between components;
    · A compound selected from the group consisting of mineral wool, fiberglass and cellulose, which improve tensile strength; 35
    · Manganese salts, which are oxidizing additives that increase asphalt stiffness once mixed with it and spread;
    · Lead and / or calcium, as antioxidant compounds that improve the product's half-life; Y
    · Amines, which improve water resistance. 5

    The invention contemplates that the second component incorporates one of these additives, or any combination thereof. Preferably, each of these additives, when they are part of the mixture of the second component, can be contained therein between 0% and 15%, ie up to 15% of the total weight of the mixture 10 of the second component. , and is more preferably contained between 1% and 15% of the total weight of the mixture of the second component.

    In a preferred embodiment of the invention, among the additional additives described above, the mixture of the second component comprises: polymers of the styrene-15-butadiene-styrene (SBS) and styrene-butadiene (SBR) type, amines, polyphosphoric acid (PPVA), low density polyethylene, manganese salts and ethyl vinyl acetate.

    In the most preferred case of all, the bituminous composition object of protection has the following formulation:
    - the first component, which is a bitumen or a mixture of bitumens that are commercial bitumens selected between 15/25 and 50/70 (in the most preferred case, is a bitumen and is 50/70 commercial bitumen), at 70% by weight of the total composition; Y
    - the second component, in a percentage of 30% of the total weight of the composition, which is a mixture containing:
    or the bitumen consisting of hydrocarbons with a number of carbon atoms equal to or greater than 13, more preferably equal to or greater than 23, and having a boiling point equal to or greater than 490 ° C, being more preferably at least 495 ° C, in a percentage of 30% of the total weight of the mixture of the second component;
    or glycerin, in a percentage of 10% of the total weight of the mixture of the second component;
    or the antioxidant gum, which is N-1,3-dimethylbutyl-N’-phenyl-p-phenylenediamide, in a percentage of 1.25% of the total weight of the mixture of the second
    component;
    or the fatty acid mixture, in a percentage of 20% of the total weight of the mixture of the second component;
    or the methyl ester, in a percentage of 10% of the total weight of the mixture of the second component; and 5
    or the paraffin resin, in a percentage of 5% of the total weight of the mixture of the second component;
    or the styrene-butadiene-styrene polymer (SBS) in a percentage of 5% of the total weight of the mixture of the second component;
    or styrene butadiene rubber (SBR) in a percentage of 5% of the total weight of the mixture of the second component;
    or the amines, in a percentage of 10% of the total weight of the mixture of the second component;
    or polyphosphoric acid (PPVA), in a percentage of 15% of the total weight of the mixture of the second component; fifteen
    or low density polyethylene (LDPE), in a percentage of 1.25% of the total weight of the mixture of the second component;
    or manganese salts, in a percentage of 1.25% of the total weight of the mixture of the second component; Y
    or ethyl vinyl acetate, in a percentage of 1.25% of the total weight of the mixture 20 of the second component.

    This bituminous composition, in any of the variants presented, shows favorable and suitable conditions for the regeneration of roads, roads, streets, etc., in such a way that it is designed to be incorporated into the milling or recyclable asphalt material (known as RAP). ) extracted from a route, by mixing as an additive, and then reusing said RAP on the route, with improved properties (see Example 4). Said recycled and regenerated RAP can even be used thanks to the bituminous composition described herein as a tread, without the need to be covered by additional layers. In addition, thanks to this bituminous composition it is possible to regenerate a track or road by RAP or milling to obtain a layer or envelope with a bearing capacity similar to that of a layer made of new generation hot agglomerate.

    Thus, another object of protection of this invention is constituted by a recyclable asphaltic material (or RAP -reclaimed asphalt pavement-, also referred to as milling here) which comprises as an additive the bituminous composition described above, and which is useful for the road regeneration and road signs. Preferably, the amount of bituminous composition containing 5 is between 1% and 5% of the total weight of RAP, more preferably between 1% and 3% of the total weight of RAP, and more preferably still being 1.4% of the weight From rap.

    It has been found that if this RAP or recyclable asphalt material extracted from a track and mixed with the bituminous composition to reintroduce it in the same way has even more potentiated properties in terms of its regeneration and reuse capacity, for example in terms of at the initial acquired hardness or the preserved strength, if said RAP containing the bituminous composition further comprises a component that is a filler additive for improvement of the preserved strength of the product. Preferably, this filler additive for improvement of the preserved strength is a mineral additive selected from lime and cement, although they are non-limiting cases of the invention (it can be, for example, fly ash). This additive acts not only as a cohesive of the mixture, but also absorbs moisture, fills the gaps and provides rigidity to the product, and in a global way improves the preserved strength of the mixture. Thus, if the additive is added to the bituminous composition-RAP in an amount between 1% and 5% of the total weight of the mixture, preferably 1%, the properties appear to be ideal and optimal for regenerating the pathway by said mixture. . These results obtained here are in line with the study conducted by Reyes, O.J. and 25 Rincon, J.F. (2009): Influence of the characteristics of the mineral filler on the resistance of an asphalt mixture; EIA Magazine, Number 11, p. 93-103.

    A third object of the present invention consists in a method of manufacturing the bituminous composition described above, in any of its variants, which comprises the step of:
    - mixing the first component with the second component at a temperature between 110ºC and 150ºC including both limits.

    The mixing temperature will depend on the bitumen or bitumens of the first component to be used, although the described temperature is the most suitable since it is guaranteed that the bitumen or bitumens of the first component are in a liquid state when it is desired to mix with the second component , facilitating its management without increases or unnecessary energy costs. In the most preferred case, the mixing temperature of the two components is 120 ° C, below which the bitumen tends to solidify. The mixing can be carried out by means of a manual or industrial stirrer, without this determining aspect for the properties of the final bituminous product obtained. The same goes for the revolutions at which the components are mixed. 10

    In a particular embodiment, the first component that is one or more bitumens is already in liquid form (hot, contained in a cistern that maintains the proper temperature); if this bitumen or bitumen mixture has a temperature to liquefy higher than is necessary in the process, then it is necessary to let the first liquid component lose temperature, for example by letting it cool, until it reaches the temperature required for the mixture With the second component. In another alternative embodiment, the first component may be in a solid state (a cold block) before mixing with the second component; in this case, it is necessary to include a step of heating the bitumen 20 or mixture of bitumen until it is melted, before proceeding with mixing with the second component.

    The second component may already be mixed and ready in accordance with the formulations described above herein, such that it is mixed with the first component. In another alternative, it is possible to manufacture this second component prior to mixing with the first, so that the method can include a previous step to prepare the second component, by mixing its constituent elements, in situ, that is, where it goes to be mixed with the first to manufacture the bituminous composition. 30

    After mixing, the bituminous composition is stable at room temperature. In this way, after the manufacturing process it can be stored in drums, tanks ... prior to its use or commercialization, without the need for
    presence of heat to keep it in a liquid state, as is the case with bitumens that are used as raw material in this process.

    Another object of the present invention is constituted by the use of the bituminous composition for the asphalt and firm regeneration, or what is the same, a method 5 for regenerating asphalt and firm which comprises mixing the bituminous composition with a recyclable asphalt material ( RAP), also known as milling in the technical field, cold, before spreading the mixture in the space where you want to regenerate the firm, either the same route from which the RAP was extracted or a different one.
     10
    By "cold mixing" it should be understood at a temperature between 0 ° C and 60 ° C; It is called cold because of the significant temperature difference of this process with hot and cold mixtures. In a more preferred case, the mixture of the bituminous composition and the RAP is carried out at room temperature, the ambient temperature being understood to be that which ranges between 25 ° C and 15 ° C, including both limits. This is one of the most outstanding aspects of this method of regeneration of pavements by means of the bituminous composition object of protection of this patent, since on the one hand, in contrast to other materials and methods of recycling of RAP, it is not necessary to preheat the additive of regeneration because at room temperature it remains stable and liquefied in such a way that it is manageable to reheat the RAP because it is liquid, and on the other it is carried out without the need to reheat the RAP. In this way, it can be affirmed that its use guarantees an environmental sustainability never reached in the sector thanks to the fact that it can be used cold, without requiring the prior heating of the RAP before mixing and pouring or without heating the bituminous composition itself so that 25 be manageable, mandatory steps in the mixing processes in temperate and hot due to the use of bitumen. In addition, this method allows reusing 100% of the milling of the old firm (which is also considered waste, depending on the areas / countries), a result that cannot be achieved with other known methods, such as temperate temperature mixtures. 30

    The composition-RAP mixture to be used in the regeneration of pavement is obtained by mixing the RAP with an amount of bituminous composition preferably between 1% and 5% of the total weight of RAP, plus
    preferably with an amount between 1% and 3% of the total weight of RAP, and more preferably even an amount of 1.4% of the total weight of RAP.

    It has been found that in a particular case the envelope obtained from the RAP-bituminous composition mixture is optimized when the RAP or milling has a previous humidity between 1% and 10%, being more preferably between 2% and 3%.

    In addition, in the most preferred case, the process may comprise a step of adding a filler additive for the improvement of the preserved strength of the material, as defined above. This filler additive is preferably selected from lime and cement, although it may be another valid for this case as fly ash. This element should be added in a percentage between 1% and 5% of the total weight, although preferably 1%. Thus, the product obtained and to be used in the regeneration of the road or firm has 15 properties even more enhanced for the interest sought (see Example 3). If this additive is added, the firm regeneration method comprises first mixing the RAP with this additive for improving the strength preserved, and then adding the bituminous composition of interest to the mixture in the second place. twenty

    As it is a cold technology (that is, at temperatures such as those described above and well below warm and temperate mixtures) and thanks to the properties of the bituminous composition (which does not carry water), its use and the regeneration of Firm is not limited to the summer months, as is the usual procedure in relation to the construction and recycling of roads today, due to the limitations of existing technologies, but it can be applied at any time of the year. In fact, the temperature range of use of the composition when it is to be mixed with the milling, in any of the exposed cases, is wide, showing no appreciable changes between -50ºC and 30 80ºC.

    In addition, both the manufacture of the bituminous composition and its application in the asphalt regeneration process can be carried out using existing machinery, that is to say without any specific machinery, which does not do
    A large investment in infrastructure and machinery is necessary. Thus, the manufacturing process can be carried out in situ or ex situ, specifically: in continuous hot chipboard manufacturing plants, without requiring the heating of the heaters; discontinuous hot agglomerate manufacturing plants; cold agglomerate manufacturing plants; concrete manufacturing plants; 5 or discontinuous mobile plants for mixing in situ, recycling machinery for recycling on site and, in general, any machinery manufactured for this purpose. In this way, the use of the bituminous composition to reuse and recycle RAP, and the method of firm and track regeneration allows the same path from which the RAP is extracted to be regenerated, or using the mixture prepared for a different route. 10

    The bituminous composition object of the present invention is designed to be used as an additive product in the regeneration of asphalts and road surfaces, which offers the possibility of recovering the old agglomerate, milling (RAP) constituting the roads and streets, returning its properties mechanics 15 through an environmentally sustainable method that allows the reuse of its components. Even this method comprises regenerating the firm in such a way that the RAP-bituminous composition mixture in any of its variants is used as a tread. In this case, the firm regeneration method comprises a final stage in which once the bitumen-20 RAP composition mixture is extended, said mixture is subjected to surface irrigation to avoid the loss of fine aggregate, as is usual in the field of cold road recycling. For this, any composition known in this work area can be used, such as, preferably, the bituminous surface treatment composition TL2000, as described in US Patent 7,041,717 B2, although it can also be the emulsion 25 type ECL1 or similar.

    In short, the invention thus covers not only the bituminous composition described and its method of obtaining, together with an RAP comprising said composition as an additive and which is going to be used in the asphalt regeneration, but also a method of use (application ) of the bituminous composition described to regenerate road surfaces and asphalts. Said method comprises mixing said composition with the milling coming from the road, street or stockpile (RAP), which is lifted and extracted from the place of origin. The quantity to be used depends on the characteristics of the milling to be regenerated (residual bitumen, granulometry of the constituent aggregates of the same…), and 35
    it ranges as said in a variable proportion between 1% and 5% by weight of bituminous composition with respect to said milling. In particular, for road sign regeneration, the amount of bituminous composition is preferably between 1% and 3% by weight of the total milling, with 1.4% by weight of the total milling (RAP) being more preferable. 5

    This regeneration process can be carried out in situ, that is, in the place where the milling is lifted and extracted (normally in the case of road sign regeneration), or at least in the place where it is going to applied regenerated milling, or ex situ, that is to say in any plant designed for that purpose to which the raised firm is transported for mixing with the composition of interest (in these cases, the bitumen-RAP composition mixture can be stored until use, for example in drums). The latter case may be more advisable when it is desired to prepare a mixture of composition and RAP that is to be stored for use on demand in the track bump. fifteen

    DESCRIPTION OF THE FIGURES
    FIGURE 1. Comparison image of a road or firm road regenerated by cold recycling without a tread (1a) and a road regenerated and recovered with the bituminous composition of Example 2 as used in Example 20 4 (1b).

    EXAMPLES
    Example 1. Preparation of a bituminous composition for the regeneration of road surfaces in accordance with the present invention. 25
    In this case, a bituminous composition of formulation 70:30 was prepared, which has 70% of the first component and 30% of the second. The bitumen used as the first component is a 50/70 commercial bitumen, which was in a liquid state and which was mixed with the second component of the following formulation at a temperature of 120 ° C: 30
    or bitumen consisting of hydrocarbons with a number of carbon atoms greater than 23 and having a boiling point greater than 495 ° C, in a percentage of 15% of the total weight of the mixture of the second component;
    or glycerin, in a percentage of 10% of the total weight of the mixture of 35
    second component;
    or antioxidant gum, which is N-1,3-dimethylbutyl-N’-phenyl-p-phenylenediamide, in a percentage of 1.25% of the total weight of the mixture of the second component;
    or mixture of fatty acids, in a percentage of 20% of the total weight of the mixture of the second component;
    or methyl ester, in a percentage of 10% of the total weight of the mixture of the second component; Y
    or paraffin resin, in a percentage of 5% of the total weight of the mixture of the second component; 10
    or styrene-butadiene-styrene polymer (SBS) in a percentage of 5% of the total weight of the mixture of the second component;
    or styrene butadiene rubber (SBR) in a percentage of 5% of the total weight of the mixture of the second component;
    or amines, in a percentage of 10% of the total weight of the mixture of the second component;
    or polyphosphoric acid (PPVA), in a percentage of 15% of the total weight of the mixture of the second component;
    or low density polyethylene (LDPE), in a percentage of 1.25% of the total weight of the mixture of the second component; twenty
    or manganese salts, in a percentage of 1.25% of the total weight of the mixture of the second component; Y
    or ethyl vinyl acetate, in a percentage of 1.25% of the total weight of the mixture of the second component.
     25
    Once the bituminous composition was obtained, it was mixed with RAP or milling extracted from a route, in an amount of composition of 1.4% of the total weight of RAP. The mixture with the RAP was carried out at a temperature of 30 ° C in a hot agglomerate plant, without the need to light the burners because it is not necessary to heat the RAP or the bituminous composition, in steps of ± 3 Tm. 30 To optimize the envelope, the milling or RAP was previously modified to the mixture so that it presented a degree of humidity between 2% and 3%.

    Example 2. Preparation of a bituminous roadside regenerating composition according to the present invention, for track bump. 35
    In this case, a 50:50 formulation bituminous composition was prepared, which has 50% of each of the two components described herein. The bitumen used is also in this case a 50/70 bitumen, which was in a liquid state and which was mixed with the second component of the following formulation at a temperature of 120 ° C: 5
    or bitumen consisting of hydrocarbons with a number of carbon atoms greater than 23 and having a boiling point greater than 495 ° C, in a percentage of 15% of the total weight of the mixture of the second component;
    or glycerin, in a percentage of 10% of the total weight of the mixture of the second component;
    or antioxidant gum, which is N-1,3-dimethylbutyl-N’-phenyl-p-phenylenediamide, in a percentage of 1.25% of the total weight of the mixture of the second component;
    or mixture of fatty acids, in a percentage of 20% of the total weight of the mixture of the second component;
    or methyl ester, in a percentage of 10% of the total weight of the mixture of the second component; Y
    or paraffin resin, in a percentage of 5% of the total weight of the mixture of the second component; twenty
    or styrene-butadiene-styrene polymer (SBS) in a percentage of 5% of the total weight of the mixture of the second component;
    or styrene butadiene rubber (SBR) in a percentage of 5% of the total weight of the mixture of the second component;
    or amines, in a percentage of 10% of the total weight of the mixture of the second component;
    or polyphosphoric acid (PPVA), in a percentage of 15% of the total weight of the mixture of the second component;
    or low density polyethylene (LDPE), in a percentage of 1.25% of the total weight of the mixture of the second component; 30
    or manganese salts, in a percentage of 1.25% of the total weight of the mixture of the second component; Y
    or ethyl vinyl acetate, in a percentage of 1.25% of the total weight of the mixture of the second component.
     35
    Once the bituminous composition was obtained, it was mixed with RAP or milling extracted from a route, in an amount of 3% of the total weight of the RAP. The mixing was carried out at a temperature of 30ºC in plant, although it could also have been carried out in concrete mixer. After mixing, it was packaged in drums for use on demand, since the properties of the mixture allow it. 5

    Example 3. Laboratory analysis of the bituminous compositions object of protection for regeneration of milled material or RAP.
    An object of interest was to analyze in the laboratory the effect on the properties of the mixture of the bituminous composition with the milling or RAP, as well as the effect when adding additive components of improvement of conservation of resistance. Thus, first, the properties of the composition-RAP mixture obtained in accordance with Example 1 of the present invention were analyzed, to subsequently analyze different alternatives: a mixture composed of bituminous composition, RAP and also 1% lime, per one side, and a mixture of bituminous composition and RAP and 15 adding 1% cement to it. The curing of the specimens used for the laboratory study was carried out outdoors and at room temperature.

    Table 1. Properties of the RAP recycle mix with the bituminous composition described in Example 1 20
     AGE  RECYCLING MIXTURE (1.4% BITUMINOUS COMPOSITION)
     DENSITY (g / cm3)  IMMERSION TEST COMPRESSION
     RCS (MPa) (DRY)  RCS (MPa) (HUM.) IRC (%)
     7 DAYS  2.25 1.9 1.1 60.0
     15 DAYS  2.25 2.1 1.4 64.5
     30 DAYS  2.26 2.3 1.5 65.2

    Table 2. Comparative study between the RAP recycling mix with the bituminous composition described in Example 1, and the same mixture with 1% cement
     AGE  RECYCLING MIXTURE (1.4% BITUMINOUS COMPOSITION) AND 1% CEMENT
     DENSITY  IMMERSION TEST COMPRESSION
     (g / cm3)  RCS (MPa) (DRY) RCS (MPa) (HUM.) IRC (%)
     7 DAYS  2.21 2.1 2.1 100
     15 DAYS  2.20 2.3 1.9 82.6
     30 DAYS  2.21 2.4 2.3 95.8
     60 DAYS  2.21 2.5 2.3 92.0

    Table 3. Comparative study between the RAP recycling mix with the bituminous composition described in Example 1, and the same mixture with 1% lime
     AGE  RECYCLING MIXTURE (1.4% BITUMINOUS COMPOSITION) AND 1% CAL
     DENSITY (g / cm3)  IMMERSION TEST COMPRESSION
     RCS (MPa) (DRY)  RCS (MPa) (HUM.) IRC (%)
     7 DAYS  - - - -
     15 DAYS  2.19 2.5 2.5 100
     30 DAYS  2.19 2.7 3.0 111
     60 DAYS  - - - -

    These results confirmed the possibility of incorporating mineral elements such as 5 lime and cement, which increase the hardness of the mixture formed by milling extracted from a path and the bituminous composition that is added for its regeneration and incorporation into the path, mainly improve the resistance Preserved product.

    Example 4. Use of the bituminous composition defined in Example 1 for the regeneration of a road sign: TO1927 road.
    The TO1927 road is a road belonging to the Diputación de Toledo, where a pilot study has been carried out for the regeneration of the damaged land. Several work of milling / replacement of the firm was carried out with the bituminous composition as described in Example 1 in one of the directions of the track, and with hot agglomerate in the other direction, the section being 1 km. 6 cm of firm were milled, it was transferred to a plant and 100% mixed with the bituminous composition with a proportion of 1.4% by weight of the composition, discarding only what was going through the sieve of 25. He brought the mixture back to work,
    extending the milling mixed with the composition at room temperature (about 30 ° C) and compacting it with a roller and with pneumatic compactor like any conventional hot bituminous mixture.

    To prevent the loss of fine aggregate, irrigation was carried out with a surface treatment product known as TL2000, in an amount of 400 grams per square meter of track. The latter was clearly more effective when operating as a rolling layer without any protective coating that would be required in the case of using traditional cold-recycled firm products, and presenting a favorable appearance after 12 months of commissioning. . 10

    The physical and mechanical characteristics of the regenerated firm were analyzed one year after its application. A visual inspection of the surface characteristics of the rolling layer executed with the composition was performed, as well as an extraction in control specimens for laboratory tests. fifteen

    A year later, 10 control specimens of 100 mm in diameter were extracted, 3 to analyze Marshall parameters, 6 for water sensitivity and 1 in laboratory track deformation. The tests to determine the physical and mechanical characteristics of the bituminous layer were: 20
    - NLT 159/200. Determination of Marshall parameters.
    - UNE-EN 12697-12: 2009 Bituminous mixtures. Test methods for hot bituminous mixtures. Part 12: Determination of the water sensitivity of bituminous test specimens.
    - UNE-EN 12697-22: 2008 + A1: 2008. Bituminous mixtures Test methods 25 for hot bituminous mixtures. Part 22: Rolling test.
    - UNE-EN 12697-26: 2012 ANNEX C. Bituminous mixtures. Test methods for hot bituminous mixtures. Part 26: Rigidity.

    Visual inspection 30
    Superficially, the tread layer executed with the mixture did not present pathologies such as loss of aggregates, loss of mastic, cracks, ruts or potholes. The appearance of the layer is very similar to that of any bituminous hot mix asphaltic concrete.
    Laboratory tests 35
    Marshall parameters
    - Apparent density (g / cm3): 2,337
    - Marshall Stability (KN): 7.9
    - Marshall deformation: 3.2
    Water sensitivity: 5
    - Indirect tensile strength (ITS) (Kpa):
    Wet specimens: 1684.5
    · Dry test tubes: 1904.0
    - Indirect tensile strength ratio (%): 88.5
    Rolling test 10
    - WTS air (mm / 103): 0.088
    - PRD air (%): 5,070
    - RD (mm): 3,043
    · Rigidity modules
    - Stiffness module (Mpa): 4021.25 15
    - Rigidity module 0.60 (Mpa): 4004.02

    The Marshall density obtained is very similar to that of hot mixtures with this aggregate, but without the need to use such high temperatures or with excessive consumption of heat energy. As for Marshall stability, the value obtained is less than usual for hot bituminous mixtures (MBC); However, we must not forget the two criteria to take into account for all the tests carried out:
    - They are tests on control specimens. The usual tests on MBCs are carried out with specimens prepared in the laboratory and therefore with better manufacturing conditions than the controls.
    - They are trials at a certain age, so this parameter can continue to rise over time.

    The Marshall deformation obtained is very similar to that of hot mixes. The 30 indirect tensile strengths obtained are very similar to those of hot bituminous concrete mixtures type AC S bituminous, therefore although the Marshall stability is somewhat lower, the support capacity of the mixture estimated with the indirect tensile test indicates which is similar to MBCs, although comparatively hot they are more expensive, energy and raw material 35
    (virgin aggregates are used), and it is a value not achieved so far with cold or temperate firm recycling.

    The PG-3 requests, in section 542.5.1.4 of Water Sensitivity: In any circumstance, the adhesive-binding bond will be checked by characterization 5 of the water action. For this, the resistance conserved in the indirect tensile test after immersion, carried out at fifteen degrees Celsius (15 ° C), according to UNE-EN 12697-12, will have a minimum value of eighty percent (80%) for base layers and intermediate, and eighty-five percent (85%) for rolling layers. The result obtained of 88.5% exceeds the minimum values requested by PG-3 for the use of bituminous concrete mixtures (Article 542) for rolling layers.

    According to the rolling test, the firm regenerated with the bituminous composition can be used as a rolling layer for:
    - Up to T3 traffic for all zones.
    - Up to T2 traffic for the middle and temperate zones.
    - For all traffic in temperate zone.

    Regarding stiffness, the results obtained in accordance with the UNE-EN-12697-26, 20 Annex C standard in the different control specimens tested at 20 ° C are shown in the following Table 4.

    Table 4. Stiffness results in accordance with standard UNE-EN-12697-26, annex C.
     SSD DENSITY (Mg / m3) RIGIDITY MODULE (MPa) RIGIDITY MODULE 0.60 (MPa)
     Witness 1  2,339 3,741,929 3,748,761
     Witness 2  2,339 4,109,927 4,110,255
     Witness 3  2,300 4,151,891 4,153,051
     Half  2,326.00 4,001.25 4,004.02
     Deviation  22.51 225.55 222.10
     CV  0.0097 0.0564 0.0555
    25
    权利要求:
    Claims (16)
    [1]

    1. A bituminous roadside regenerating composition, characterized in that it comprises:
    - a first component that is a bitumen or a mixture of bitumens in a 5 percentage range between 40% and 80% by weight of the total composition; Y
    - a second component that is a mixture that contains:
    or a bitumen, in a percentage comprised between 5% and 20% of the total weight of the mixture of the second component, consisting of hydrocarbons 10 with a number of carbon atoms equal to or greater than 13 and having a boiling point equal to or higher than 490 ° C;
    or glycerin, in a percentage between 5% and 10% of the total weight of the mixture of the second component;
    or antioxidant gum, in a percentage equal to or less than 1.50% of the total weight of the mixture of the second component;
    or a mixture of fatty acids, in a percentage between 1% and 30% of the total weight of the mixture of the second component;
    or a methyl ester, in a percentage comprised between 1% and 30% of the total weight of the mixture of the second component; and 20
    or paraffin resin, in a percentage between 1% and 30% of the total weight of the mixture of the second component.

    [2]
    2. The bituminous composition of the preceding claim, the second component is contained in a percentage comprised between 20% and 60% by weight of the total composition.

    [3]
    3. The bituminous composition according to any one of claims 1 or 2, wherein the first component is contained in 70% of the total weight of the composition and the second component in 30% of the total weight of the composition. 30

    [4]
    4. The bituminous composition according to any one of the preceding claims, wherein the bitumen or bitumens of the first component are commercial type 15/25 or type 50/70.
     35
    [5]
    5. The bituminous composition according to any one of claims 1 to 4, wherein the bitumen of the mixture of the second component is a residue obtainable from the vacuum distillation of a residue which in turn comes from the distillation at atmospheric pressure of the oil to temperatures above 490 ° C.
     5
    [6]
    6. The bituminous composition according to any one of claims 1 to 5, wherein the bitumen hydrocarbons of the second component have a number of carbon atoms equal to or greater than 23, and said bitumen has a boiling point of at least 490 ° C.
     10
    [7]
    7. The bituminous composition according to any one of claims 1 to 6, comprising:
    - the first component, which is a bitumen or a mixture of bitumens, in a percentage between 40% and 80% by weight of the total composition; and 15
    - the second component, which is a mixture that contains:
    or the bitumen consisting of hydrocarbons with a number of carbon atoms equal to or greater than 23 and having a boiling point equal to or greater than 490 ° C, in a percentage of 15% of the total weight of the mixture of the second component; twenty
    or glycerin, in a percentage of 10% of the total weight of the mixture of the second component;
    or the antioxidant gum, which is N-1,3-dimethylbutyl-N'-phenyl-p-phenylenediamide, in a percentage of 1.25% of the total weight of the mixture of the second component; 25
    or the fatty acid mixture, in a percentage of 20% of the total weight of the mixture of the second component;
    or the methyl ester, in a percentage of 10% of the total weight of the mixture of the second component; Y
    or the paraffin resin, in a percentage of 5% of the total weight of the mixture of the second component.

    [8]
    8. The bituminous composition according to any one of claims 1 to 7, wherein the mixture of the second component comprises one or more additional additives selected from the group consisting of:
    · An elastomeric polymer of the styrenic type that is SBS, to prevent the formation of grooves, delay and reduce the onset of fatigue and increase the resistance to thermal breakage;
    · Styrene-butadiene rubber, to prevent the formation of grooves, delay and reduce the appearance of fatigue and increase the resistance to thermal breakage; 5
    · Low density polyethylene, for the improvement of resistance to furrow formation at high temperatures;
    · A thermoplastic polymer that is ethyl vinyl acetate, for the improvement of resistance to furrow formation at high temperature;
    · A thermoplastic polymer that is ethylene-propylene, for the improvement of resistance to thermal breakage;
    · Crumb rubber, to avoid the formation of grooves, delay and reduce the appearance of fatigue and increase the resistance to thermal breakage;
    · Polyphosphoric acid, for the improvement of resistance to high temperatures;
    · Sulfur and / or lignin, as a binder or binder; fifteen
    · Lime, to fill gaps, increase stability and improve the bond between components;
    · A compound selected from the group consisting of mineral wool, fiberglass and cellulose, which improve tensile strength;
    · Manganese salts, which are oxidizing additives that increase the stiffness of asphalt once mixed with it and spread;
    · Lead and / or calcium, as antioxidant compounds that improve the product's half-life; Y
    · Amines, which improve water resistance,
    and any combination thereof. 25

    [9]
    9. The bituminous composition according to the preceding claim, which has the following formulation:
    - the first component, which is a 50/70 bitumen, at 70% by weight of the total composition; and 30
    - the second component, in a percentage of 30% of the total weight of the composition, which is a mixture containing:
    or the bitumen consisting of hydrocarbons with a number of carbon atoms equal to or greater than 23 and having a boiling point equal to or greater than 490 ° C, at a percentage of 15% of the total weight of 35
    the mixture of the second component;
    or glycerin, in a percentage of 10% of the total weight of the mixture of the second component;
    or the antioxidant gum, which is N-1,3-dimethylbutyl-N'-phenyl-p-phenylenediamide, in a percentage of 1.25% of the total weight of the mixture of the second component;
    or the fatty acid mixture, in a percentage of 20% of the total weight of the mixture of the second component;
    or the methyl ester, in a percentage of 10% of the total weight of the mixture of the second component; and 10
    or the paraffin resin, in a percentage of 5% of the total weight of the mixture of the second component;
    or the styrene-butadiene-styrene polymer in a percentage of 5% of the total weight of the mixture of the second component;
    or styrene butadiene rubber in a percentage of 5% of the total weight of the mixture of the second component;
    or the amines, in a percentage of 10% of the total weight of the mixture of the second component;
    or polyphosphoric acid, in a percentage of 15% of the total weight of the mixture of the second component; twenty
    or low density polyethylene, in a percentage of 1.25% of the total weight of the mixture of the second component;
    or manganese salts, in a percentage of 1.25% of the total weight of the mixture of the second component; Y
    or ethyl vinyl acetate, in a percentage of 1.25% of the total weight of the mixture 25 of the second component.

    [10]
    10. A method of manufacturing the composition defined in any one of claims 1 to 9, characterized in that it comprises the step of:
    - mixing the first component with the second component at a temperature between 110 ° C and 150 ° C including both limits.

    [11]
    11. A recyclable asphalt material (RAP) comprising as additive the bituminous composition described in any one of claims 1 to 9 in an amount between 1% and 5% of the total weight of recyclable asphalt material. 35

    [12]
    12. The recyclable asphalt material according to the preceding claim, further comprising a filler additive for improving the preserved strength of the material, selected from lime and cement, in an amount between 1% and 5% of the total weight. 5

    [13]
    13. Use of the bituminous composition described in any one of claims 1 to 9 as an asphalt regenerative additive and road sign.

    [14]
    14. The use according to the preceding claim, which comprises mixing the bituminous composition 10 with a recyclable asphalt material which is a milling previously extracted and lifted from a pathway, in an amount of bituminous composition comprised between 1% and 5% of the total weight of mixture and at a temperature between 0 ° C and 60 ° C, to subsequently spread the mixture in the same way or in a different way.
     fifteen
    [15]
    15. The use according to any one of claims 13 or 14, which comprises mixing the milling previously extracted and lifted in one way with a filler additive to improve the strength preserved, selected from lime and cement, in an amount between 1 % and 5% of the total weight, prior to mixing the milled material with the additive that is the bituminous composition. twenty

    [16]
    16. The use according to any one of claims 13 to 15, wherein the mixture of asphaltic material and bituminous composition is used as a rolling layer in a path to be regenerated.
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    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US6013681A|1995-10-09|2000-01-11|Kao Corporation|Production of bituminous emulsion and liquid amine emulsifier therefor|
    EP2192158A1|2008-11-28|2010-06-02|Colas|Asphalt binder for the production of lukewarm mixtures|
    US20130295394A1|2012-05-01|2013-11-07|Keith C. Hong|Roofing product including bio-based asphalt mixture and methods of making the roofing product and the roofing-grade asphalt mixture|
    US20140130712A1|2012-11-14|2014-05-15|Colas|Binder modified with glycerol for making asphalt mixes with a hicontent of recycled bituminous materials|CN112694286A|2021-01-14|2021-04-23|山东省交通科学研究院|Multifunctional extremely-thin surface layer material for road and application thereof|
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